An Organoytterbium(III) Complex Exhibiting Field-Induced Single-Ion-Magnet Behavior.

Inorg Chem

∥Institut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objets, Université de Montpellier, ENSCM, CNRS, Place E. Bataillon, 34095 Montpellier Cedex 5, France.

Published: August 2015

We present a new mononuclear half-sandwich complex, [Cp*Yb(DAD)(THF)]·C7H8 (1), based on a paramagnetic Yb(III) ion coordinated by diamagnetic Cp* and enediamido[2,6-Me2C6H3NCH═CHNC6H3Me2-2,6](2-) (DAD) ligands exhibiting field-induced single-ion-magnet behavior.

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http://dx.doi.org/10.1021/acs.inorgchem.5b01318DOI Listing

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