Solvent scales used to study the intermolecular interactions in binary solutions of two p-aryl-pyridazinium methylids.

Spectrochim Acta A Mol Biomol Spectrosc

Alexandru Ioan Cuza University, Faculty of Physics, Carol I Bvd., RO-700506, Iasi, Romania. Electronic address:

Published: January 2016

The visible electronic absorption band with intramolecular charge transfer of two pyridazinium ylids having common carbanion and different heterocycles is recorded in solutions and its position is correlated to parameters of some empirical scales of solvents. The nature of the intermolecular interactions in pyridazinium ylid solutions is discussed and the supply of each type of interaction is established based on solvatochromic study.

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http://dx.doi.org/10.1016/j.saa.2015.07.006DOI Listing

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