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Eight isostructural lanthanide coordination polymers [Ln(bptc)(phen)(H2O)]n (Ln = Dy for , Eu for , Tb for , Gd for , Sm for , Nd for , Yb for , Pr for ) were successfully prepared based on bridging asymmetric polycarboxylate ligand biphenyl-3,2',5'-tricarboxylic acid (H3bptc) and chelating 1,10-phenanthroline (phen) coligand. Single crystal X-ray analysis reveals that complexes have a (3,6)-connected CdI2-type coordination network consisting of paddle-wheel dimers [Ln2(CO2)4]. The magnetic and fluorescent properties of have been investigated. Significantly, the Dy(iii) complex behaves with slow relaxation of the magnetization, where the frequency-dependent out-of-phase signals are noticed.
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http://dx.doi.org/10.1039/c5dt01894c | DOI Listing |
Chem Commun (Camb)
December 2024
Institute of Inorganic Chemistry (AOC), Karlsruhe Institute of Technology (KIT), Kaiserstr. 12, 76131, Karlsruhe, Germany.
Cyclononatetraenyl (Cnt) is a nine-membered monoanionic aromatic ligand. Despite its early discovery in 1963, it has been rarely utilised in coordination chemistry, which is mainly due to its large diameter and easy skeletal rearrangement. Only in 2017, the first lanthanide Cnt complex was synthesised, marking the beginning of a new era in organolanthanide chemistry.
View Article and Find Full Text PDFChem Asian J
December 2024
IIT delhi, department of chemistry, Hauz Kahs, 110016, New Delhi, INDIA.
The crystallization of lanthanide-containing β-octamolybdate (β-{Mo8O26}4-) based solids from a binary 1:1 (water/DMSO) solution under ambient conditions is reported. A uniform synthetic protocol yielded three structurally related series of general composition {Ln(solvent)n}[NaMo8O26]·yH2O, with the whole lanthanide series (except for radioactive Pm). The three series are (i) {Ln(DMSO)8}[NaMo8O26]·0.
View Article and Find Full Text PDFJ Phys Chem A
December 2024
Department of Chemical and Materials Engineering, University of Nevada Reno, Reno, Nevada 89557, United States.
Single-molecule magnets (SMMs) with slow relaxation of magnetization and blocking temperatures above that of liquid nitrogen are essential for practical applications in high-density data storage devices and quantum computers. A rapid and accurate prediction of the effective magnetic relaxation barrier () is needed to accelerate the discovery of high-performance SMMs. Using density functional theory and multireference calculations, we explored correlations between , partial atomic charges, and the anisotropic barrier for a series of sandwich-type lanthanide complexes containing cyclooctatetraene, substituted cyclopentadiene, phospholyl, boratabenzene, or borane ligands.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, PR China. Electronic address:
Bovine serum albumin (BSA) is one of the most abundant proteins in serum, and its high-throughput detection is still one of the current challenges. Nitrogen‑phosphorus co-doped carbon dots (CDs) were synthesized by a hydrothermal method. Adenosine monophosphate (AMP) was used as a precursor for the synthesis of CDs, providing the required carbon, nitrogen and phosphorus sources for the CDs.
View Article and Find Full Text PDFMikrochim Acta
December 2024
Department of Chemistry, College of Science, University of Sulaimani, Qliasan St. 46002, Sulaymaniyah, Kurdistan Region, Iraq.
An efficient dual-state blue-emitting zinc-based metal-organic frameworks (MOFs), designated as UoZ-8 has been developed. Coordination-induced emission causes the UoZ-8 to give the blue emission in both solid and dispersed form in liquid. Upon the addition of tetracycline (TC), a noticeable shift from blue emission to greenish-yellow emission occurred, with a marked increase in intensity, which was attributed to the inner filter effect accompanied by aggregation-induced emission (IFE-AIE).
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