We introduce the multi-dimensional permutation-modulation format in coherent optical communication systems and analyze its performance, focusing on the power efficiency and the spectral efficiency. In the case of four-dimensional (4D) modulation, the polarization-switched quadrature phase-shift keying (PS-QPSK) modulation format and the polarization quadrature-amplitude modulation (POL-QAM) format can be classified into the permutation modulation format. Other than these well-known modulation formats, we find novel modulation formats trading-off between the power efficiency and the spectral efficiency. With the increase in the dimension, the spectral efficiency can more closely approach the channel capacity predicted from the Shannon's theory. We verify these theoretical characteristics through computer simulations of the symbol-error rate (SER) and bit-error rate (BER) performances. For example, the newly-found eight-dimensional (8D) permutation-modulation format can improve the spectral efficiency up to 2.75 bit/s/Hz/pol/channel, while the power penalty against QPSK is about 1 dB at BER=10(-3).
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http://dx.doi.org/10.1364/OE.23.015587 | DOI Listing |
Adv Sci (Weinh)
January 2025
Jihua Hengye Electronic Materials Co. Ltd., Foshan, Guangdong, 528200, P. R. China.
B- and N-heterocyclic fluorophores have reveal promising efficiency in blue organic light-emitting diodes (OLEDs) with small full-width-at-half-maximum (FWHM). However, their structural determinants for spectral broadening and operating stability are still needed to be investigated in further. Herein, a novel multi-N-heterocycles Diindolo[3,2,1jk:3',2',1'jk]dicarbazole[1,2-b:4,5-b] (DIDCz) is proposed to manipulate the emission color toward pure blue region by extending π-conjugation of the N-π-N bridge.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Departament de Farmàcia i Tecnologia Farmacèutica, i Fisicoquímica, Facultat de Farmàcia i Ciències de l'Alimentació, Universitat de Barcelona (UB), 08028 Barcelona, Spain.
Incorporation of environment and vibronic effects in simulations of optical spectra and excited state dynamics is commonly done by combining molecular dynamics with excited state calculations, which allows to estimate the spectral density describing the frequency-dependent system-bath coupling strength. The need for efficient sampling, however, usually leads to the adoption of classical force fields despite well-known inaccuracies due to the mismatch with the excited state method. Here, we present a multiscale strategy that overcomes this limitation by combining EMLE simulations based on electrostatically embedded ML potentials with the QM/MMPol polarizable embedding model to compute the excited states and spectral density of 3-methyl-indole, the chromophoric moiety of tryptophan that mediates a variety of important biological functions, in the gas phase, in water solution, and in the human serum albumin protein.
View Article and Find Full Text PDFJ Chem Theory Comput
January 2025
Chemical Physics Theory Group, Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 3H6.
The cost of encoding a system Hamiltonian in a digital quantum computer as a linear combination of unitaries (LCU) grows with the 1-norm of the LCU expansion. The Block Invariant Symmetry Shift (BLISS) technique reduces this 1-norm by modifying the Hamiltonian action on only the undesired electron-number subspaces. Previously, BLISS required a computationally expensive nonlinear optimization that was not guaranteed to find the global minimum.
View Article and Find Full Text PDFBrief Bioinform
November 2024
Department of Biology, University at Albany, SUNY, 1400 Washington Ave, Albany, NY 12222, United States.
The accuracy of assigning fluorophore identity and abundance, known as spectral unmixing, in biological fluorescence microscopy images remains a significant challenge due to the substantial overlap in emission spectra among fluorophores. In traditional laser scanning confocal spectral microscopy, fluorophore information is acquired by recording emission spectra with a single combination of discrete excitation wavelengths. However, organic fluorophores possess characteristic excitation spectra in addition to their unique emission spectral signatures.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Tokyo Electron America, Inc., 2400 Grove Blvd., Austin, Texas 78741, United States.
Photoresists are thin film materials designed to transform an optimal image into a mechanical mask. Diverse exposure techniques such as photolithography induce modifications in the exposed areas that result in solubility changes that can then be selectively removed with appropriate agents (developers). Photoresist materials need to keep pace with the increasingly demand for feature size reduction.
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