A novel structure for thin-film solar cells is simulated with the purpose of maximizing the absorption of light in the active layer and of reducing the parasitic absorption in other layers. In the proposed structure, the active layer is formed from an amorphous silicon thin film sandwiched between silicon nanowires from above and photonic crystal structures from below. The upper electrical contact consists of an indium tin oxide layer, which serves also as an antireflection coating. A metal backreflector works additionally as the other contact. The simulation was done using a new reliable, efficient and generic optoelectronic approach. The suggested multiscale simulation model integrates the finite-difference time-domain algorithm used in solving Maxwell's equation in three dimensions with a commercial simulation platform based on the finite element method for carrier transport modeling. The absorption profile, the external quantum efficient, and the power conversion efficiency of the suggested solar cell are calculated. A noticeable enhancement is found in all the characteristics of the novel structure with an estimated 32% increase in the total conversion efficiency over a cell without any light trapping mechanisms.
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http://dx.doi.org/10.1364/AO.54.005534 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
National Renewable Energy Lab, Golden, Colorado 80401, United States.
Cd(Se,Te) photovoltaics (PV) are the most widely deployed thin-film solar technology globally, yet continued efficiency improvements are stymied by challenges at the device hole contacts. The inclusion of solution-processed oxide layers such as AlGaO in the contact stack has yielded improved device open-circuit voltages () and fill factors (FF). However, contradictory mechanisms by which these layers improve the device properties have been proposed by the research community.
View Article and Find Full Text PDFNanoscale
January 2025
Laboratory of Quantum Functional Materials Design and Application, School of Physics and Electronic Engineering, Jiangsu Normal University, Xuzhou 221116, China.
Two-dimensional materials with a combination of a moderate bandgap, highly anisotropic carrier mobility, and a planar structure are highly desirable for nanoelectronic devices. This study predicts a planar BeP monolayer with hexagonal symmetry that meets the aforementioned desirable criteria using the CALYPSO method and first-principles calculations. Calculations of electronic properties demonstrate that the hexagonal BeP monolayer is an intrinsic semiconductor with a direct band gap of approximately 0.
View Article and Find Full Text PDFThis paper explores optimization strategies for polymeric materials in organic solar cells (OSCs) with the focus on varying alkyl side chain, addition of fluorine atom, and thiophenated derivatives onto polymer. As such, it outlines the significance of renewable energy sources and the potential of photovoltaic technologies, particularly organic photovoltaics (OPVs). Objectives include factors affecting power conversion efficiency (PCE), open-circuit voltage (Voc), aggregation tendencies, and optoelectronic properties in OPVs.
View Article and Find Full Text PDFChem Asian J
January 2025
CSIR-National Chemical Laboratory: CSIR National Chemical Laboratory, Catalysis and Inorganic Chemistry Division, Dr. Homi Bhabha Road, 411 008, Pune, INDIA.
Present work describes a sol-gel assisted one-pot synthesis of mesoporous Fe₂O₃-TiO₂ nanocomposites (TiFe) with different Ti:Fe ratios, and fabrication of Ag-integrated with TiFe nanocomposites (TiFeAg) by a chemical reduction method and demonstrated for high solar H2 generation activity in direct sunlight. Enhanced solar H2 production is attributed to the light absorption from entire UV+Visible region of solar spectrum combined with Schottky (Ag-semiconductor) and heterojunctions (TiO2-Fe2O3), as evidenced from HRTEM and various characterization studies. TiFeAg-2 thin film (1 wt% Ag-loaded TiFe-4) displayed the highest activity with a solar H2 yield of 7.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
School of Integrated Circuits and Electronics, Beijing Institute of Technology, Beijing 100081, P. R. China.
Efficient thermal generation from solar/electric energy in transparent films remains challenging due to the limited toolbox of high-performance thermal generation materials and methods for microstructure engineering. Here, we proposed a two-step strategy to introduce hierarchical wrinkles to the MXene composite films with high transparency, leading to upgraded photo/electrothermal conversion efficiency. Specifically, the thin film contains protic acid-treated MXene layers assembled with Ag nanowires (H-MXene/Ag NWs).
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