Producing energy from biomass and other organic waste residues is essential for sustainable development. Fraunhofer UMSICHT has developed a novel reactor which introduces the Thermo-Catalytic Reforming (TCR®) process. The TCR® is a process which can convert any type of biomass and organic feedstocks into a variety of energy products (char, bio-oil and permanent gases). The aim of this work was to demonstrate this technology using digestate as the feedstock and to quantify the results from the post reforming step. The temperature of a post reformer was varied to achieve optimised fuel products. The hydrogen rich permanent gases produced were maximised at a post reforming temperature of 1023 K. The highly de-oxygenated liquid bio-oil produced contained a calorific value of 35.2 MJ/kg, with significantly improved fuel physical properties, low viscosity and acid number. Overall digestate showed a high potential as feedstock in the Thermo-Catalytic Reforming to produce pyrolysis fuel products of superior quality.
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http://dx.doi.org/10.1016/j.wasman.2015.07.001 | DOI Listing |
Polymers (Basel)
February 2024
Chemical and Environmental Engineering Department, Faculty of Engineering of Bilbao, University of the Basque Country (UPV/EHU), Plaza Ingeniero Torres Quevedo, 1, 48013 Bilbao, Spain.
Waste carbon fibre-reinforced plastics were recycled by pyrolysis followed by a thermo-catalytic treatment in order to achieve both fibre and resin recovery. The conventional pyrolysis of this waste produced unusable gas and hazardous liquid streams, which made necessary the treatment of the pyrolysis vapours. In this work, the vapours generated from pyrolysis were valorised thermochemically.
View Article and Find Full Text PDFiScience
December 2022
Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore 117585, Singapore.
Zeolite-based catalytic membrane reactors have been successfully applied in overcoming the thermodynamic limitations of CO hydrogenations and dry reforming of methane (DRM) reactions. This review summarizes the zeolites as membrane reactor components regarding the permeance, permselectivity, durability, conversion, selectivity, and stability by referring to the synergy of catalyst and membrane. Also, five operation parameters (temperature, pressure, feed ratio, sweeping gas flow rate, and gas hourly space velocity) are introduced regarding their impacts on the performance of membrane reactor.
View Article and Find Full Text PDFCatal Sci Technol
October 2021
Laboratory of Catalysis and Catalytic Processes, Dipartimento di Energia, Politecnico di Milano Via La Masa 34 20156 Milano Italy
The increasing environmental concerns due to anthropogenic CO emissions have called for an alternate sustainable source to fulfill rising chemical and energy demands and reduce environmental problems. The thermo-catalytic activation and conversion of abundantly available CO, a thermodynamically stable and kinetically inert molecule, can significantly pave the way to sustainably produce chemicals and fuels and mitigate the additional CO load. This can be done through comprehensive knowledge and understanding of catalyst behavior, reaction kinetics, and reactor design.
View Article and Find Full Text PDFGlob Change Biol Bioenergy
September 2020
Biorefining Group Institute of Biological, Environmental and Rural Sciences Aberystwyth University Aberystwyth UK.
Pyrolysis char residues from ensiled macroalgae were examined to determine their potential as growth promoters on germinating and transplanted seedlings. Macroalgae was harvested in May, July and August from beach collections, containing predominantly and ; naturally seeded mussel lines dominated by ; and lines seeded with cultivated . Material was ensiled, pressed to pellets and underwent pyrolysis using a thermo-catalytic reforming (TCR) process, with and without additional steam.
View Article and Find Full Text PDFEnergy Fuels
October 2019
School of Chemical Engineering, University of Birmingham, Edgbaston, Birmingham B15 2TT, U.K.
Food and market waste (FMW) is one of the most abundant unrecycled products which poses waste management issues and negative environmental impacts. Thermo-catalytic reforming (TCR) is a pyrolysis based technology which can convert a wide range of biomass wastes into energy vectors bio-oil, syngas, and char. This paper investigates the conversion potential of FMW into sustainable biofuels.
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