KCTf3, a commercially available, easily handled neutral salt, enhanced the reaction rates and the chemical yields of a wide spectrum of cationic metal catalyzed reactions, ranging from traditional Lewis acid catalysis to transition metal catalysis.
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The glassy state of inorganic-organic hybrid metal halides combines their excellent optoelectronic properties with the outstanding processability of glass, showcasing unique application potential in solar devices, display technologies, and plastic electronics. Herein, by tailoring the organic cation from -phenylpiperazine to dimethylamine gradually, four types of zero-dimensional antimony halides are obtained with various optical and thermal properties. The guest water molecules in crystal (-phenylpiperazine)SbCl·Cl·5HO lead to the largest distortion of the Sb-halogen unit, resulting in the red emission different from the yellow emission of other compounds.
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Department of Biochemistry, University of Zurich, Zurich, Switzerland.
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