A hydrogen bond acceptor plays an important role in the catalytic cycle of organo-enamine catalysis. It can effectively influence the rate of reaction through hydrogen bonding interaction with enammonium (N-protonated enamine intermediate). Our findings are supported by both kinetic experiments and quantum chemical calculations.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/chem.201502407 | DOI Listing |
Publication Analysis
Top Keywords
organo-enamine catalysis
8
role hydrogen-bonding
4
hydrogen-bonding acceptors
4
acceptors organo-enamine
4
catalysis hydrogen
4
hydrogen bond
4
bond acceptor
4
acceptor plays
4
plays role
4
role catalytic
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!