A cyanine-based dithienylethene is developed. Its photoisomerization shows that (1) the irradiation of visible light can induce cyclization while the cycloreversion takes place upon irradiation with UV light and (2) the addition of CN(-) can lead to cyclization and cycloreversion upon irradiation of UV light and visible light, respectively.
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Visible-Light-Dependent Photocyclization: Design, Synthesis, and Properties of a Cyanine-Based Dithienylethene.
J Org Chem
August 2015
†Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
A cyanine-based dithienylethene is developed. Its photoisomerization shows that (1) the irradiation of visible light can induce cyclization while the cycloreversion takes place upon irradiation with UV light and (2) the addition of CN(-) can lead to cyclization and cycloreversion upon irradiation of UV light and visible light, respectively.
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