Controlling the flexibility and single-crystal to single-crystal interpenetration reconstitution of metal-organic frameworks.

Chem Commun (Camb)

MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.

Published: August 2015

By changing the ligand substituent groups near the open metal sites from hydrophilic to hydrophobic, the guest-induced structural dynamism of a series of isostructural 5-fold interpenetrated MOFs changed from interpenetration reconstitution to simple framework breathing.

Download full-text PDF

Source
http://dx.doi.org/10.1039/c5cc05036gDOI Listing

Publication Analysis

Top Keywords

interpenetration reconstitution
8
controlling flexibility
4
flexibility single-crystal
4
single-crystal single-crystal
4
single-crystal interpenetration
4
reconstitution metal-organic
4
metal-organic frameworks
4
frameworks changing
4
changing ligand
4
ligand substituent
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!