How to restrain the dissolution of polysulfides from the sulfur cathode is the current research focus of Li-S batteries. Here, we find that moderate dissolution of polysulfides is of great importance for high-efficiency and stable discharge/charge cycling. Both overprotection and inadequate protection of the sulfur cathode are unfavorable for the cycling of Li-S batteries.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/c5cc03753k | DOI Listing |
Small
January 2025
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, 100029, P. R. China.
The electrocatalytic conversion of 16-electron multistep polysulfides is crucial for lithium-sulfur batteries, while it is hard to achieve compatibility between intricate sulfur reduction processes and appropriate catalysts. Herein, a tandem conversion strategy is reported to boost multi-step intermediate reactions of polysulfides transformation by designing an electrocatalyst featuring cobalt and zinc sites (Co/Zn), where the Zn serve as sites for the conversion of long-chain lithium polysulfides (LiPSs), promoting the transformation of S to LiS; the Co sites accelerate the kinetics of the subsequent reduction of LiS. This tandem catalysis method not only enhances the conversion of the initial reactants but also provides additional support for the intermediates, thereby facilitating subsequent reactions to maximize capacity.
View Article and Find Full Text PDFNat Mater
January 2025
Department of Mechanical Engineering, The Pennsylvania State University, University Park, PA, USA.
Lithium-sulfur (Li-S) all-solid-state batteries (ASSBs) hold great promise for next-generation safe, durable and energy-dense battery technology. However, solid-state sulfur conversion reactions are kinetically sluggish and primarily constrained to the restricted three-phase boundary area of sulfur, carbon and solid electrolytes, making it challenging to achieve high sulfur utilization. Here we develop and implement mixed ionic-electronic conductors (MIECs) in sulfur cathodes to replace conventional solid electrolytes and invoke conversion reactions at sulfur-MIEC interfaces in addition to traditional three-phase boundaries.
View Article and Find Full Text PDFChemSusChem
January 2025
Washington State University, School of Mechanical and Materials Engineering, PO Box 642920, 99164-2920, Pullman, UNITED STATES OF AMERICA.
Advancement of sulfur (S) cathode of lithium-sulfur (Li-S) batteries is hindered by issues such as insulating nature of sulfur, sluggish redox kinetics, polysulfide dissolution and shuttling. To address these issues, we initiate a study on applying an important amino acid of protein, arginine (Arg), as a functional additive into S cathodes. Based on our simulation study, the positively charged Arg facilitates strong interactions with polysulfides.
View Article and Find Full Text PDFChem Asian J
January 2025
Charotar University of Science and Technology, Physical Science, P.D. Patel Institute of Applied Sciences, 388421, Changa, INDIA.
The primary obstacle in electrolyzing water is that prolonged large-current operation quickly degrades performance, making it difficult to achieve efficient and continuous hydrogen evolution at high current densities. This work prepared sulfur-doped nickel ferrite nanocomposites using the simple hydrothermal method to improve electrocatalytic green hydrogen production at high-current densities. X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) were used to analyze the crystalline structure, morphology, and chemical composition of the synthesized nanocomposites.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Wenzhou University, College of Chemistry and Materials Engineering, Chashan University Town, 325035, Wenzhou, CHINA.
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!