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Grape marc as a source of carbohydrates for bioethanol: Chemical composition, pre-treatment and saccharification. | LitMetric

Grape marc as a source of carbohydrates for bioethanol: Chemical composition, pre-treatment and saccharification.

Bioresour Technol

The Australian Research Council Centre of Excellence in Plant Cell Walls, School of Agriculture, Food and Wine, University of Adelaide, Waite Campus, Glen Osmond, South Australia 5064, Australia. Electronic address:

Published: October 2015

AI Article Synopsis

  • Global grape production results in significant waste, with up to 13 million tons of grape marc generated each year, which is being explored as a potential source for biofuel.
  • The analysis of Cabernet Sauvignon and Sauvignon Blanc grape marc shows that it is rich in carbohydrates, with a considerable portion being soluble in water, and contains valuable compounds like polyphenols and cellulose.
  • Pre-treatments, such as sulfuric acid, can enhance the extraction of glucose for bioethanol production, projecting a potential yield of up to 400 liters of bioethanol per ton of grape marc, while also producing a byproduct that could be used for animal feed or fertilizer.

Article Abstract

Global grape production could generate up to 13 Mt/yr of wasted biomass. The compositions of Cabernet Sauvignon (red marc) and Sauvignon Blanc (white marc) were analyzed with a view to using marc as raw material for biofuel production. On a dry weight basis, 31-54% w/w of the grape marc consisted of carbohydrate, of which 47-80% was soluble in aqueous media. Ethanol insoluble residues consisted mainly of polyphenols, pectic polysaccharides, heteroxylans and cellulose. Acid and thermal pre-treatments were investigated for their effects on subsequent cellulose saccharification. A 0.5M sulfuric acid pre-treatment yielded a 10% increase in the amount of liberated glucose after enzymatic saccharification. The theoretical amount of bioethanol that could be produced by fermentation of grape marc was up to 400 L/t. However, bioethanol from only soluble carbohydrates could yield 270 L/t, leaving a polyphenol enriched fraction that may be used in animal feed or as fertilizer.

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Source
http://dx.doi.org/10.1016/j.biortech.2015.06.030DOI Listing

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