Biomimetic self-assembling acylphthalocyanines.

Chem Commun (Camb)

Aix-Marseille Université, CNRS UMR 7313, Centrale Marseille, Chirosciences, Service 442, Avenue Escadrille Normandie-Niemen, F-13013 Marseille, France.

Published: July 2015

We synthesized a series of biomimetic self-assembling phthalocyanines equipped with carbonyl groups as recognition motifs, a central zinc atom and diverse solubilizing alkyl chains mimicking for the first time with these robust pigments the natural chlorosomal bacteriochlorophylls. Upon self-assembly a very broad and red-shifted Q-band absorption extending to over 900 nm is put into evidence.

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http://dx.doi.org/10.1039/c5cc04602eDOI Listing

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