Reactions of 5-(9H-carbazol-9-yl)-isophthalate and metal salts provide laminar metal organic frameworks (MOFs) wherein interlayer interactions of the pendant carbazoles engender extended aromatic stacks or non-stacked structures with enhanced solid-state emission. These studies emphasize that MOFs serve as versatile supramolecular platforms to direct the aggregation and electroptical behaviours of organic chromophores.
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