We report herein the synthesis of a fully functionalized B,C,D-ring system of lancifodilactone F. The key transformations involve an arene-olefin -photocycloaddition reaction and a palladium-catalyzed oxidative C-C cleavage reaction to establish its B,C-rings.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4472376 | PMC |
http://dx.doi.org/10.1016/j.tetlet.2014.12.054 | DOI Listing |
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