A difluoro(mesityl)platinum(IV) complex underwent highly selective reductive elimination of 2-fluoromesitylene upon heating in toluene. Kinetic analysis and DFT calculations suggest that the CF coupling involves a five-coordinate Pt(IV) transient intermediate resulting from the rate-limiting dissociation of the pyridine ligand.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/anie.201503116 | DOI Listing |
Publication Analysis
Top Keywords
reductive elimination
8
selective aryl-fluoride
4
aryl-fluoride reductive
4
elimination platinumiv
4
platinumiv complex
4
complex difluoromesitylplatinumiv
4
difluoromesitylplatinumiv complex
4
complex underwent
4
underwent highly
4
highly selective
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!