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Heck-Mizoroki coupling of vinyliodide and applications in the synthesis of dienes and trienes. | LitMetric
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Heck-Mizoroki coupling of vinyliodide and applications in the synthesis of dienes and trienes.

Katrina S Madden Sylvain David Jonathan P Knowles Andrew Whiting

Chem Commun (Camb)

Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, UK.

Published: July 2015

Vinyliodide reacts chemoselectively under Heck-Mizoroki conditions with terminal alkenes, including vinylboronate esters, to give dienes. The resulting dienylboronates undergo Suzuki-Miyaura couplings with aryl, heteroaryl and alkenyl halides to access dienes and trienes.

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http://dx.doi.org/10.1039/c5cc03273cDOI Listing

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