Combining graphene with plasmonics is expected to lead to new nanoscale applications such as sensors, photodetectors, and optical circuits, since graphene plasmons in the infrared have relatively low losses and are easily tunable. It was shown that the edges of a graphene sheet completely reflect these plasmons with negligible radiation losses. Here, however, we examine structured graphene edges, which provide the ability to tailor and even completely cancel the reflection. These properties depend on the suitable dimensions of the edge grating. We explain the reflection modulation via the appearance of longitudinal Fabry-Perot type modes. Interesting phase changes and resonances appear when the longitudinal modes interact with lateral modes mediated by edge plasmons.
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http://dx.doi.org/10.1364/OL.40.002727 | DOI Listing |
Chemistry
December 2024
Ulsan National Institute of Science and Technology, Chemistry, UNIST-gil 50, Bldg.108, Rm901-5, 44919, Ulsan, KOREA, REPUBLIC OF.
Nanographenes and polycyclic aromatic hydrocarbons, both finite forms of graphene, are promising organic semiconducting materials because their optoelectronic and magnetic properties can be modulated through precise control of their molecular peripheries. Several atomically precise edge structures have been prepared by bottom-up synthesis; however, no systematic elucidation of these edge topologies at the molecular level has been reported. Herein, we describe rationally designed modular syntheses of isomeric dibenzoixenes with diverse molecular peripheries, including cove, zigzag, bay, fjord, and gulf structured.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Center for Nano and Micro Mechanics, Tsinghua University, Beijing, China.
Static friction, a ubiquitous physical phenomenon, plays a significant role in natural processes and industrial applications. Its influence is particularly notable in the field of controlled micromanipulation and precision manufacturing, where static friction often exceeds kinetic friction and leads to material damage and unpredictable behaviors. In this study, we report the first experimental observation of the elimination of static friction peak in sliding micrometer contacts of layered materials, achieved through a technique involving selective etching of the amorphous edges of single crystalline surfaces.
View Article and Find Full Text PDFChem Asian J
December 2024
Northwest Normal University, College of Chemistry and Chemical Engineering, CHINA.
In this paper, a new carbon dot (R1-CDs) was prepared by one-pot hydrothermal method by using 1,8-diaminonaphthalene and o-phthalic acid (o-PA) as precursors. Due to the high purity of R1-CDs, NMR analysis was performed to identify the types of H and C atoms in their graphene sheets. From our research findings, three important information was disclosed such as (1) five types H atoms are presented in R1-CDs; (2) 18 kinds of C atoms in the graphene sheets are observed, and 8 kinds of them are quaternary atoms, and 10 kinds of carbon atoms as tertiary one; (3) functional groups of -COOH and -NH2 from precursors cannot be inherited into the edges or defect sites of graphene sheet.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Barrer Centre, Department of Chemical Engineering, Imperial College London, London SW7 2AZ, United Kingdom.
Graphene oxide (GO)-based membranes have demonstrated great potential in water treatment. However, microdefects in the framework of GO membranes induced by the imperfect stacking of GO nanosheets undermine their size-sieving ability and structural stability in aqueous systems. This study proposes a targeted growth approach by growing zeolitic imidazolate framework-8 (ZIF-8) nanocrystals precisely to patch microdefects as well as to cross-link the porous graphene oxide (PGO) flakes coated on the outer surface of the hollow fiber (HF) alumina substrate (named the hybrid PGO/ZIF-8 membrane).
View Article and Find Full Text PDFJ Chem Phys
December 2024
Department of Physics, University Josip Juraj Strossmayer in Osijek, Trg Ljudevita Gaja 6, Osijek 31000, Croatia.
Graphene (Gr) and hexagonal boron nitride (hBN) nanoribbons have shown significant potential for various applications owing to their unique electronic and magnetic properties. This study explored the effects of hydrogenation on the magnetic and electronic properties of Gr-hBN nanoribbons (Gr/BNNRs). The influence of hydrogenation of one or both edges, i.
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