An experimental and theoretical study of lyotropic chromonic liquid crystals (LCLCs) confined in cylinders with degenerate planar boundary conditions elucidates LCLC director configurations. When the Frank saddle-splay modulus is more than twice the twist modulus, the ground state adopts an inhomogeneous escaped-twisted configuration. Analysis of the configuration yields a large saddle-splay modulus, which violates Ericksen inequalities but not thermodynamic stability. Lastly, we observe point defects between opposite-handed domains, and we explain a preference for point defects over domain walls.
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http://dx.doi.org/10.1103/PhysRevE.91.050501 | DOI Listing |
Phys Rev E
November 2024
Department of Physics, University of California Merced, Merced, California 95343, USA.
Platinum-coated Janus colloids exhibit self-propelled motion in aqueous solution via the catalytic decomposition of hydrogen peroxide. Here, we report their motion in a uniformly aligned nematic phase of lyotropic chromonic liquid crystal, disodium cromoglycate (DSCG). When active Janus colloids are placed in DSCG, we find that the anisotropy of the liquid crystal imposes a strong sense of direction to their motion; the Janus colloids tend to move parallel to the nematic director.
View Article and Find Full Text PDFSmall
December 2024
Department of Physics, Kent State University, Kent, OH, 44242, USA.
The dynamics of swimming bacteria depend on the properties of their habitat media. Recently it is shown that the motion of swimming bacteria dispersed directly in a non-toxic water-based lyotropic chromonic liquid crystal can be controlled by the director field of the liquid crystal. Here, we investigate whether the macroscopic polar order of a ferroelectric nematic liquid crystal (N) can be recognized by bacteria B.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
September 2024
Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu, 525-8577, Japan.
ACS Appl Mater Interfaces
July 2024
Department of Mechanical Engineering and Materials Science, Yale University, New Haven, Connecticut 06511, United States.
Anisotropic hydrogels have found widespread applications in biomedical engineering, particularly as scaffolds for tissue engineering. However, it remains a challenge to produce them using conventional fabrication methods, without specialized synthesis or equipment, such as 3D printing and unidirectional stretching. In this study, we explore the self-assembly behaviors of polyethylene glycol diacrylate (PEGDA), using disodium cromoglycate (DSCG), a lyotropic chromonic liquid crystal, as a removable template.
View Article and Find Full Text PDFSoft Matter
March 2024
School of Physics and Astronomy, University of Minnesota, Minneapolis, MN 55455, USA.
A singular potential method in the tensor order parameter representation of a nematic liquid crystal is used to study the equilibrium configuration of a disclination dipole. Unlike the well studied isotropic limit (the so called one constant approximation), we focus on the case of anisotropic Frank elasticity (bend/splay elastic constant contrast). Prior research has established that the singular potential method provides an accurate description of the tensor order parameter profile in the vicinity of a disclination core of a highly anisotropic lyotropic chromonic liquid crystal.
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