Mechanical wear accounts for one third of present global energy consumption. However, it still lacks an efficient lubricant to simultaneously achieve a highly efficient lubrication and metal wear repair. Herein, we report that carbon quantum dots (CQDs)/CuSx nanocomposites show enhanced lubrication and metal wear surface repair abilities when used as additives. The highly efficient lubrication and metal wear repair properties should be attributed to the combination of the multi-layer graphite structure of CQDs and the high chemical activity of CuSx nanoparticles.
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http://dx.doi.org/10.1039/c5nr01923k | DOI Listing |
Sci Total Environ
January 2025
Department of Environmental Health Sciences, School of Public Health, University of Michigan, Ann Arbor, MI, 48109, United States. Electronic address:
Polychlorinated naphthalenes (PCNs) and polychlorinated biphenyls (PCBs) are toxic contaminants that were produced and used in large quantities for their stability, inertness, and other desirable electrical, cooling, and lubricating properties. Due to their environmental persistence and improper disposal, these contaminants have become broadly distributed in the environment. This study examines the levels, composition, distribution, and potential sources of these compounds in surface soils and street dusts collected at 19 residential and industrial areas in Detroit, Michigan.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Seoul National University of Science & Technology, Department of Chemical and Biomolecular Engineering, 232 Gongneung-ro, 01811, Seoul, KOREA, REPUBLIC OF.
Depolymerizing plastic waste through hydrogen-based processes, such as hydrogenolysis and hydrocracking, presents a promising solution for converting plastics into liquid fuels. However, conventional hydrogen production methods rely heavily on fossil fuels, exacerbating global warming. This study introduces a novel approach to plastic waste hydrogenolysis that utilizes in situ hydrogen generated via the aqueous phase reforming (APR) of methanol, a biomass-derived chemical offering a more sustainable alternative.
View Article and Find Full Text PDFRSC Adv
January 2025
Norwegian Tribology Center, Department of Mechanical and Industrial Engineering, Norwegian University of Science and Technology (NTNU) Trondheim Norway
The focus on energy efficiency to move towards a more sustainable use of resources has intensified efforts to minimize friction and wear in mechanical systems, which account for 23% of the world's energy consumption. In this study, polyoxometalate ionic liquids (POM-ILs) are introduced as environmentally acceptable lubricant additives, for their potential friction-reducing and anti-wear (AW) properties. These compounds, characterized by their complex structures and tunable properties, have been investigated for their tribological performance across base fluids of varying polarities.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Centre for Advanced Laser Manufacturing (CALM), School of Mechanical Engineering, Shandong University of Technology, Zibo 255000, P. R. China.
Developing versatile, scalable, and durable coatings that repel various matters in different service environments is of great importance for engineered materials applications but remains highly challenging. Here, the mesoporous silica microspheres (HMS) fabricated by the hard template method were utilized as micro-nanocontainers to encapsulate the hydrophobic agent of perfluorooctyltriethoxysilane (F13) and the corrosion inhibitor of benzotriazole (BTA), forming the functional microsphere of F-HMS(BTA). Moreover, the synthesized organosilane-modified silica sol adhesive (SMP) and F-HMS(BTA) were further employed as the binder and functional filler to construct a superhydrophobic self-healing coating of SMP@F-HMS(BTA) on various engineering metals through scalable spraying.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Institute for Engineering Design and Product Development, Research Unit Tribology E307-05, TU Wien, Vienna, 1060, Austria.
Metal-organic framework (MOF) nanoparticles have attracted widespread attention as lubrication additives due to their tunable structures and surface effects. However, their solid lubrication properties have been rarely explored. This work introduces the positive role of moisture in solid lubrication in the case of a newly described Ti-based MOF (COK-47) powder.
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