Crystal structure of trans-dihydrido-bis[tris-(di-methyl-amino)-phosphane-κP]platinum(II).

Acta Crystallogr E Crystallogr Commun

Department of Chemistry and Biochemistry, 1253 University of Oregon, Eugene, Oregon 97403-1253, USA.

Published: April 2015

The mol-ecule of the title compound, [PtH2(C6H18N3P)2], has a centrosymmetric square-planar structure in which the Pt(II) atom is bonded to two H and two P atoms in a mutually trans configuration. The Pt(II) atom sits on an inversion center and thus the asymmetric unit contains only half the mol-ecule. The Pt-P and Pt-H distances are 2.2574 (10) and 1.49 (7) Å, respectively.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438795PMC
http://dx.doi.org/10.1107/S2056989015004351DOI Listing

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