AI Article Synopsis
- A reaction involving [(COD)IrCl]2, HCl, and indene aimed to produce a chlorido-indenyliridium dimer.
- Instead, the reaction yielded an octahedral iridium(III) complex, [IrCl3(CH3CN)(C8H12)], which includes a chelating cyclo-octa-1,5-diene ligand, three chloride ligands arranged in a fac configuration, and one acetonitrile ligand.
- Efforts to create a systematic approach for synthesizing this compound were not successful.
Article Abstract
A reaction between [(COD)IrCl]2 (COD is cyclo-octa-1,5-diene), HCl and indene failed to provide the hoped for chlorido-indenyliridium dimer, but instead produced the title compound, [IrCl3(CH3CN)(C8H12)], which is an octa-hedral complex of iridium(III) with a chelating cyclo-octa-1,5-diene ligand, three chloride ligands in a fac arrangement, and one aceto-nitrile ligand. Attempts to devise a rational synthesis for the title compound were unsuccessful.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4438853 | PMC |
| http://dx.doi.org/10.1107/S2056989015004855 | DOI Listing |
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