A dysprosium-zinc porphyrin, [DyZn(TPPS)H3O]n (1) (TPPS = tetra(4-sulfonatophenyl)porphyrin), was prepared through solvothermal reactions and structurally characterized by single-crystal X-ray diffraction analyses. Complex 1 features a three-dimensional (3-D) porous open framework that is thermally stable up to 400 °C. Complex 1 displays a void space of 215 Å(3), occupying 9.2% of the unit cell volume. The fluorescence spectra reveal that it shows an emission band in the red region. The fluorescence lifetime is 39 µsec and the quantum yield is 1.7%. The cyclic voltammetry (CV) measurement revealed one quasi-reversible wave with E1/2 = 0.30 V.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/bio.2938 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Pyrene functionalized organic cation receptor-based "turn-on" fluorescence approach for monitoring of chlorpyrifos in food, soil, and water samples.
Anal Chim Acta
January 2025
Department of Chemistry, Indian Institute of Technology Ropar, Rupnagar, Punjab, 140001, India. Electronic address:
Background: The unregulated use of pesticides by farmers, for crop productivity results in widespread contamination of organophosphates in real environmental samples, which is a growing societal concern about their potential health effects. The conventional approaches for the monitoring these organophosphate-based pesticides which include immunoassays, electrochemical methods, immunosensors, various chromatography techniques, along with some spectroscopic methods, are either costly, sophisticated, or involves the use of different metal complexes. Therefore, there is an urgent need for sensitive, quick, and easy-to-use detection techniques for the screening of widely used organophosphate-based pesticides.
View Article and Find Full Text PDFNaphthalene Diimide-Embedded Donor-Acceptor Carbon Nanohoops: Photophysical, Photoconductive, and Charge Transport Properties.
ACS Appl Mater Interfaces
January 2025
College of Chemistry, Beijing Normal University, Beijing 100875, China.
Designing the architecture of donor-acceptor (D-A) pairs is an effective strategy to tailor the electronic structure of conjugated macrocycles for optoelectronic devices. Herein, we present the synthesis of three D-A nanohoops ( = 7, 8, 9) containing a naphthalene diimide (NDI) unit as an acceptor and []cycloparaphenylenes ([]CPPs) moieties as donors. The D-A characteristics of were substantiated through absorption and fluorescence spectroscopic studies, electrochemical investigations, and computational analysis.
View Article and Find Full Text PDFAn Anthracene-imidazoanthraquinone Conjugate Exhibiting Ratiometric Fluorescence Turn - On Behavior with CN- and F- Anions.
Chempluschem
January 2025
Banaras Hindu University, Chemistry, Institute of Science, 221005, Varanasi, INDIA.
A new conjugate, 2-(4-(anthracen-9-yl) phenyl)-[1,2-d]imidazole-1H-anthraquninone (AQI) has been designed and synthesized as a molecular probe 4. The photophysical and electrochemical behavior of the probe in the absence and presence of different class of ions were examined in acetonitrile solution. The probe 4 with F- and CN- anions showed ratiometric fluorescence "turn - On" response due to variation in ICT processes.
View Article and Find Full Text PDFOptimal Synergy between Azulenes and Acenes in Azuacenes with 6-7-5 Ring Topology.
J Am Chem Soc
January 2025
Department of Physical Chemistry, University of Malaga, Campus de Teatinos s/n, Málaga 29071, Spain.
Azuacenes, defined as azulene fused with acenes in a 6-7-5 ring topology and spanning lengths from 3 to 6 rings, have been synthesized using a new skeleton editing and [3 + 2] annulation synthesis protocol as a distinction regarding the procedures to obtain the 6-5-7 isomers. Comprehensive studies on ground-state and excited-state spectroscopy, electrochemical properties, chemical stability, and solid-state structure have been conducted to compare these azuacenes with acenes. For the same number of rings, we found that azuacenes improve the chemical stability of acenes (i.
View Article and Find Full Text PDFN-Doped Zigzag-Type Aromatic Truncated Cone Belts.
J Am Chem Soc
January 2025
Key Laboratory of Bioorganic Phosphorous and Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
Zigzag aromatic hydrocarbon belts, ultrashort segments of zigzag carbon nanotubes, have been fascinating in the chemistry community for more than a half century because of their aesthetically appealing molecular nanostructures and tantalizing applications. Precise introduction of heteroatoms of distinct electronegativity and electronic configuration can create various heterocyclic aromatic nanobelts with novel physical and chemical properties. Here, we report the synthesis of unprecedented N-doped zigzag-type aromatic belts, belt[]pyrrole[]pyridines ( = 6-8), from multiple intramolecular C-C homocoupling reactions of readily available azacalix[](3,5-dibromopyridine)s.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!