Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 143
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 994
Function: getPubMedXML
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3134
Function: GetPubMedArticleOutput_2016
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
We focus on two classes of organic switches operating due to the photo- or field-induced proton transfer (PT) process. By means of first-principles simulations, we search for the atomic contacts that strengthen diversity of the two swapped current-voltage (I-V) characteristics between two tautomers. We emphasize that the low-resistive contacts do not necessarily possess good switching properties. Very often, the higher-current flow makes it more difficult to distinguish between the logic states. Instead, the more resistive contacts multiply a current gear to a larger extent. The low- and high-bias work regimes set additional conditions, which are fulfilled by different contacts: (i) in the very low-voltage regime, the direct connections to the nanotubes perform better than the popular sulfur contacts, and (ii) in the higher-voltage regime, the best are the peroxide (-O-O-) contacts. Additionally, we find that the switching-bias value is not an inherent property of the conducting molecule, but it strongly depends on the chosen contacts.
Download full-text PDF |
Source |
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http://dx.doi.org/10.1088/0957-4484/26/24/245201 | DOI Listing |
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