AI Article Synopsis
- A new method produces high-quality carbon monoxide by breaking down oxalyl chloride in a solution with hydroxide.
- The technique is effective for creating heterocycles and various chemical reactions involving hydroxy, alkoxy, amino, and reductive carbonylation.
- This method allows these reactions to occur under milder conditions compared to earlier approaches.
Article Abstract
A method for generation of high-quality carbon monoxide by decomposition of oxalyl chloride in an aqueous hydroxide solution is described. The usefulness of the method is demonstrated in the synthesis of heterocycles and for hydroxy-, alkoxy-, amino-, and reductive carbonylation reactions, in several cases under milder conditions than previously reported.
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| http://dx.doi.org/10.1021/acs.orglett.5b01252 | DOI Listing |
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