The title compound, C26H26N2·0.5C8H10, is the first reported characterized 2:2 product from acid-catalyzed condensation of indole with cyclo-penta-none and no other 2:2 products were observed. Recrystallization from p-xylene gave the title hemisolvate with the p-xylene mol-ecule located about an inversion center. The terminal penta-lene ring is envelope-flap disordered at the C atom farthest from the skeletal indole unit, with a refined occupancy ratio of 0.819 (4):0.181 (4). The major component has this C atom bent away from the spiro-fused cyclo-pentane ring. In the crystal, mol-ecules are connected by N-H⋯π inter-actions, forming chains along [100], and N-H⋯π and C-H⋯π inter-actions, forming chains along [001], which results in the formation of slabs parallel to (010).

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4420065PMC
http://dx.doi.org/10.1107/S2056989015007422DOI Listing

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