Circuit pitch has decreased due to the demand for high-performance and multi-functional electronic devices. This trend has increased the risk of short-circuit failures by electrochemical migration (ECM), which is the transportation of ions between the cathode and anode under electrical potential. While direct printing has emerged as a promising technology in terms of manufacturing cost and environmental issues, there are few studies about ECM in directly printed copper (Cu) nanopaste. We prepared screen-printed comb-type Cu patterns on a Si wafer with various sintering temperatures (200, 250, 300, 350 degrees C). ECM characteristics of the printed Cu were determined by water drop testing under various electrical potentials (3, 6, 9 V). The microstructures and the roughness profiles of the pattern surfaces were identified with field emission scanning electron microscopy (FE-SEM) and a three-dimensional surface profiler, respectively. While the electrical potential increased from 3 V to 9 V, the time to failure (ECM time) required for dendrites to grow from the cathode to the adjacent anode decreased by 63.0%. On the other hand, the ECM time increased by 205.1% when the sintering temperature increased from 200 degrees C to 350 degrees C. FE-SEM micrographs and energy-dispersive X-ray spectroscopy analysis of dendrites showed a mixture of trunk and lace types, which were mainly composed of Cu.
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http://dx.doi.org/10.1166/jnn.2014.10152 | DOI Listing |
Small
January 2025
Department of Materials Science and State Key Laboratory of Molecular Engineering of Polymers, Academy for Engineering and Technology, Fudan University, Shanghai, 200433, P. R. China.
The transient receptor potential (TRP) channel is a key sensor for diverse cellular stimuli, regulating the excitability of primary nociceptive neurons. Sensitization of the TRP channel can heighten pain sensitivity to innocuous or mildly noxious stimuli. Here, reversible modulation of TRP channels is achieved by controlling both the light-induced photoelectrochemical reaction to induce neuronal depolarization, and antioxidants for neuronal protection.
View Article and Find Full Text PDFEntropy (Basel)
January 2025
Department of Energy and Process Engineering, Norwegian University of Science and Technology, NO-7491 Trondheim, Norway.
Electroosmosis reduces the available energy from ion transport arising due to concentration gradients across ion-exchange membranes. This work builds on previous efforts to describe the electroosmosis, the permselectivity and the apparent transport number of a membrane, and we show new measurements of concentration cells with the Selemion CMVN cation-exchange membrane and single-salt solutions of HCl, LiCl, NaCl, MgCl, CaCl and NHCl. Ionic transport numbers and electroosmotic water transport relative to the membrane are efficiently obtained from a relatively new permselectivity analysis method.
View Article and Find Full Text PDFIran J Basic Med Sci
January 2025
Tissue Engineering and stem cells research center, Shahroud University of Medical Sciences, Shahroud, Iran.
Objectives: For designing a suitable hydrogel, two crosslinked Alginate/ Carboxymethyl cellulose (Alg/CMC) hydrogel, using calcium chloride (Ca) and glutaraldehyde (GA) as crosslinking agents were synthesized and compared.
Materials And Methods: All samples were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Blood compatibility (BC), Blood clotting index (BCI), weight loss (WL), water absorption (WA), pH, and Electrochemical Impedance Spectroscopy (EIS). Cell viability and cell migration were investigated using the MTT assay and the wound scratch test, respectively.
J Am Chem Soc
January 2025
Department of Chemistry, Pohang University of Science and Technology, Pohang 37673, Republic of Korea.
Ensuring the stability of electrocatalysts is paramount to the success of electrochemical energy conversion devices. Degradation is a fundamental process involving the release of positively charged metal ions into the electric double layer (EDL) and their subsequent diffusion into the bulk electrolyte. However, despite its vital importance in achieving prolonged electrocatalysis, the underlying causality of catalyst dissolution with the EDL structure remains largely unknown.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
International Science and Technology Cooperation Base of Energy Materials and Application, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P.R. China.
Poly(ethylene oxide) (PEO) has been widely studied as an electrolyte owing to its excellent lithium compatibility and good film-forming properties. However, its electrochemical performance at room temperature remains a significant challenge due to its low ionic conductivity, narrow electrochemical window, and continuous decomposition. Herein, we prepare a multifunctional polar polymer to optimize PEO's electrochemical properties and cycling stability.
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