We study the Casimir-Polder interaction at finite temperatures between a polarizable small, anisotropic particle and a non-planar surface using a derivative expansion. We obtain the leading and the next-to-leading curvature corrections to the interaction for low and high temperatures. Explicit results are provided for the retarded limit in the presence of a perfectly conducting surface.
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http://dx.doi.org/10.1088/0953-8984/27/21/214018 | DOI Listing |
Phys Rev Lett
September 2024
LNE-SYRTE, Observatoire de Paris, Université PSL, CNRS, Sorbonne Université, 61 avenue de l'Observatoire, 75014 Paris, France.
We report on the realization of a quantum sensor based on trapped atom interferometry in an optical lattice for the measurement of atom-surface interactions, with sub-micrometer-level control of the mean atom-surface separation distance. The force sensor reaches a short-term sensitivity of 3.4×10^{-28} N at 1 s and a long-term stability of 4 qN (4×10^{-30} N).
View Article and Find Full Text PDFEntropy (Basel)
October 2023
Dipartimento di Fisica e Chimica-Emilio Segrè, Università degli Studi di Palermo, Via Archirafi 36, I-90123 Palermo, Italy.
In this review, we investigate several aspects and features of spatial field correlations for the massless scalar field and the electromagnetic field, both in stationary and nonstationary conditions, and show how they manifest in two- and many-body static and dynamic dispersion interactions (van der Waals and Casimir-Polder). We initially analyze the spatial field correlations for noninteracting fields, stressing their nonlocal behavior, and their relation to two-body dispersion interactions. We then consider how field correlations are modified by the presence of a field source, such as an atom or in general a polarizable body, firstly in a stationary condition and then in a dynamical condition, starting from a nonstationary state.
View Article and Find Full Text PDFPhys Rev Lett
October 2023
Laboratoire de Physique des Lasers, UMR 7538 du CNRS, Université Sorbonne Paris Nord, 99 av. JB Clément, 93430 Villetaneuse, France.
Near-field thermal emission largely exceeds blackbody radiation, owing to spectrally sharp emission in surface polaritons. We turn the Casimir-Polder interaction between Cs(7P_{1/2}) and a sapphire interface into a sensor sharply filtering, at 24.687 THz, the near-field sapphire emission at ∼24.
View Article and Find Full Text PDFJ Chem Theory Comput
November 2022
Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Giuseppe Moruzzi 13, 56124Pisa, Italy.
A method formulated within the polarizable continuum model of the solvent and a quantum Monte Carlo treatment of the electronic states of the solute molecule is presented for the calculation of the solute-solvent dispersion contribution to the electronic excitation energy in solution. Variational quantum Monte Carlo is exploited to measure the fluctuations of the electronic electric field of the solute molecule to compute the London's dispersion forces with the solvent. The method previously applied to the ground state of the solute is here extended to excited states.
View Article and Find Full Text PDFJ Chem Theory Comput
June 2022
Institute of Physics, Lodz University of Technology, ul. Wolczanska 217/221, 93-005, Lodz, Poland.
We address the problem of intermolecular interaction energy calculations in molecular complexes with localized excitons. Our focus is on the correct representation of the dispersion energy. We derive an extended Casimir-Polder formula for direct computation of this contribution through second order in the intermolecular interaction operator .
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