Catalytic combustion of benzene over CuO-CeO2 mixed oxides has been investigated. The CuO-CeO2 mixed oxides were prepared by the combustion method using malic acid as an organic fuel and characterized by XRD, XPS and TPR. For the CuO-CeO2 catalyst with a Cu/(Cu + Ce) molar ratio of more than 0.4, highly dispersed copper oxide species were shown at 2θ = 35.5 degrees and 38.8 degrees. The CuO-CeO2 catalyst prepared using 2.0 M malic acid showed the highest activity, with conversion reaching nearly 100% at 350 degrees C. In addition, the highest activity is shown on Cu0.40 (the index denotes the molar ratio Cu/(Cu + Ce)) sample and then it decreases on Cu0.5 and Cu0.7 samples.
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http://dx.doi.org/10.1166/jnn.2014.9950 | DOI Listing |
Materials (Basel)
March 2019
Department of Chemistry and Earth Sciences, Faculty of Arts and Sciences, Qatar University, Doha 2713, Qatar.
In this study, xCuO-CeO₂ mixed oxide catalysts (Cu weight ratio x = 1.5, 3, 4.5, 6 and 15 wt.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
May 2016
Catalytic combustion of benzene over CuO-CeO2 mixed oxides has been investigated. The CuO-CeO2 mixed oxides were prepared using various methods and characterized by XRD, BET and TPR. For the CuO-CeO2 catalysts with a Cu/(Cu + Ce) molar ratio of more than 0.
View Article and Find Full Text PDFCatalytic combustion of benzene over CuO-CeO2 mixed oxides has been investigated. The CuO-CeO2 mixed oxides were prepared by the combustion method using malic acid as an organic fuel and characterized by XRD, XPS and TPR. For the CuO-CeO2 catalyst with a Cu/(Cu + Ce) molar ratio of more than 0.
View Article and Find Full Text PDFSci Total Environ
February 2015
National Institute of Chemistry, Laboratory for Environmental Sciences and Engineering, Hajdrihova 19, SI-1001 Ljubljana, Slovenia.
The effect of nanomaterials on biota under realistic environmental conditions is an important question. However, there is still a lack of knowledge on how different illumination conditions alter the toxicity of some photocatalytic nanomaterials. We have investigated how environmentally relevant UV-A exposure (intensity 8.
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2014
Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China.
A CuO-CeO2-TiO2 catalyst for selective catalytic reduction of NOx with NH3 (NH3-SCR) at low temperatures was prepared by a sol-gel method and characterized by X-ray diffraction, Brunner-Emmett-Teller surface area, ultraviolet-visible spectroscopy, H2 temperature-programmed reduction, scanning electron microscopy and in situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS). The CuO-CeO2-TiO2 ternary oxide catalyst shows excellent NH3-SCR activity in a low-temperature range of 150-250 °C. Lewis acid sites generated from Cu(2+) are the main active sites for ammonia activation at low temperature, which is crucial for low temperature NH3-SCR activity.
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