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A Late Stage Strategy for the Functionalization of Triazolium-based NHC catalysts. | LitMetric

A Late Stage Strategy for the Functionalization of Triazolium-based NHC catalysts.

Synlett

Department of Chemistry, Colorado State University, Fort Collins, CO 80523, USA, Fax 1(970)491-1801.

Published: January 2014

A strategy for the diversification of triazolium-based catalysts is presented. This method is based on the reduction to the triazoline, which serves as a suitable and stable substrate for Pd-mediated cross-coupling, followed by trityl cation mediated reoxidation to the triazolium.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4419734PMC
http://dx.doi.org/10.1055/s-0034-1379167DOI Listing

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