A novel 3D Eu-BTB framework () containing three types of 1D channels was synthesized and structurally characterized. Compound exhibits high thermostability and water stability with the pH range from 2 to 12. Additionally, the luminescence explorations revealed that can sensitively and selectively detect pollutant PO4(3-) among various colourless anions. More importantly, represents the first example of regenerable MOF-based luminescent probes for detecting PO4(3-).
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http://dx.doi.org/10.1039/c5cc02596f | DOI Listing |
Chemistry
December 2021
Key Laboratory of Advanced Energy Materials Chemistry (MOE), College of Chemistry, Nankai University, Tianjin, 300071, P. R. China.
Entacapone (ENT) is a powerful catechol-O-methyl transferase inhibitor that is used for the diagnosis and treatment of Parkinson's syndrome, but the amount used must be well controlled to avoid overtreatment and side effect. Fast and selective detection of ENT needs well-matched energy levels and well-designed sensor-ENT interaction which is highly challenging. In this work, a water stable europium-based metal-organic framework (Eu-TDA) was synthesized to detect ENT by luminescence with excellent reusability and selectivity in the presence of main coexisting and interference species of plasma with a limit of detection of 5.
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May 2021
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China. and University of Chinese Academy of Sciences, Beijing 100049, PR China.
Water-stable anionic Ln2L2-type (Ln = LaIII and EuIII) lanthanide-organic macrocycles have been constructed by deprotonation self-assembly of a bis-tridentate ligand consisting of two 2,6-bis-(1,2,4-triazole)-pyridine chelation arms bridged by a dibenzofuran chromophore, of which the luminescent Eu2L2 macrocycle can be used for enantiomeric excess (ee) detection toward pybox-type chiral ligands and selective colorimetric sensing of omethoate (OMA) in water.
View Article and Find Full Text PDFJ Am Chem Soc
September 2020
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China.
Lanthanide-containing functional complexes have found a variety of applications in materials science and biomedicine because of their unique electroptical and magnetic properties. However, the poor stability and solubility in water of multicomponent lanthanide organic assemblies significantly limit their practical applications. We report here a series of water-stable anionic LnL-type ( = 2, 3, 4, and 5) lanthanide organic polyhedra (LOPs) constructed by deprotonation self-assembly of three fully conjugated ligands (HL and HL) featuring a 2,6-pyridine bitetrazolate chelating moiety.
View Article and Find Full Text PDFInorg Chem
April 2019
Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education), College of Chemistry and Molecular Sciences , Wuhan University, Wuhan 430072 , China.
A water-stable two-dimensional lanthanide organic framework, {Eu(BTB)DMF} (Eu-MOF; DMF = N, N-dimethylformamide), with two one-dimensional channels was obtained, and its structure was characterized. With changes in the amount of LiOH·HO, different sizes of {Eu(BTB)DMF} were synthesized. The prepared Eu-MOF powder is easy to disperse in water and exhibits typical Eu red emission.
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November 2018
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou 350007, PR China.
The development of metal-organic framework sensors with excellent stability under harsh physical and chemical conditions is of great significance in practical applications. Two isostructural lanthanide-organic frameworks, Ln-MOF ({Ln(L)(H2O)(DMA)}n, {FJU-13-Ln, Ln = Eu, Tb } (H3L = 3,5-(4-carboxybenzyloxy)benzoic acid)), were found to display exceptional stability, not only being stable in both acidic and basic aqueous solutions (pH 3-11), but also maintaining good robustness in boiling water and after activation. Furthermore, the plentiful oxygen atoms in the oxygen-rich channels of FJU-13-Eu and FJU-13-Tb acted as Lewis base sites for sensing metal ions, exhibiting high sensitivity (Stern-Volmer constant, KSV = 2.
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