Construction of unique six-coordinated titanium species with an organic amine ligand in titanosilicate and their unprecedented high efficiency for alkene epoxidation.

Le Xu Da-Ding Huang Chen-Geng Li Xinyi Ji Shaoqing Jin Zhaochi Feng Fei Xia Xiaohong Li Fengtao Fan Can Li Peng Wu

Chem Commun (Camb)

Shanghai Key Lab of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai, 200062, China.

Published: May 2015

A novel organic-inorganic layered titanosilicate consisting of Ti-containing MWW-type nanosheets and piperidine ligands was constructed. It exhibited an unprecedented high catalytic activity and recyclability in alkene epoxidation.

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http://dx.doi.org/10.1039/c5cc02321a	DOI Listing

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