Corncob, an agricultural waste, was successfully converted into a novel magnetic adsorbent by a low-temperature hydrothermal method (453K), including carbonization under saline conditions and magnetization using iron (III) salt. The resultant magnetic carbonaceous adsorbent (MCA) exhibited a porous structure with a higher specific surface area and more oxygen-containing functional groups than its carbonaceous precursor (CP), which can be attributed to the catalytic effect of Fe (III). The adsorption behaviors of both MCA and CP could be described well by Langmuir isotherm and pseudo-second-order model. The adsorption capacity for Methylene blue (MB) revealed by adsorption isotherms were 163.93mg/g on MCA and 103.09mg/g on CP, respectively. Moreover, MCA was demonstrated as a versatile adsorbent for removal of both anionic and cationic dyes, and it showed good reusability in regeneration studies. This work provides an alternative approach for effective conversion of biomass waste and application of them in pollutant removal.
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http://dx.doi.org/10.1016/j.biortech.2015.04.048 | DOI Listing |
Polymers (Basel)
December 2024
Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology, Shaanxi University of Science and Technology, Xi'an 710021, China.
This study introduces a novel water-insoluble dispersant for coal water slurry (CWS), namely, a poly(sodium styrene sulfonate)- SiO nanoparticle (SiO--PSSNa). SiO--PSSNa was synthesized by combining the surface acylation reaction with surface-initiated atom transfer radical polymerization (SI-ATRP). Fourier transform infrared spectrometry (FTIR), X-ray photoelectron spectroscopy (XPS), energy dispersive spectrometer (EDS), nuclear magnetic resonance spectroscopy (NMR) and thermogravimetric analysis (TGA) verified that SiO--PSSNa with the desired structure was successfully obtained.
View Article and Find Full Text PDFMolecules
December 2024
LAQV/REQUIMTE, Associated Laboratory for Green Chemistry, Department of Chemistry, NOVA School of Science and Technology, NOVA University Lisbon, 2829-516 Caparica, Portugal.
This paper investigates the use of spent tyre rubber as a precursor for synthesising adsorbents to recover rare earth elements. Through pyrolysis and CO activation, tyre rubber is converted into porous carbonaceous materials with surface properties suited for rare earth element adsorption. The study also examines the efficiency of leaching rare earth elements from NdFeB magnets using optimised acid leaching methods, providing insights into recovery processes.
View Article and Find Full Text PDFAnal Bioanal Chem
January 2025
State Key Laboratory of Food Science and Resources, Jiangnan University, Wuxi, 214122, China.
Ofloxacin is a commonly used quinolone antibiotic that is also used as a feed supplement in livestock production and in plant disease prevention and treatment. However, the excessive use and abuse of ofloxacin will accumulate along the food chain and endanger human health. Therefore, the development of a simple, rapid, and sensitive detection method for the determination of ofloxacin is critical.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
School of Civil Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China.
A carbon-magnetic modified sepiolite nanocomposite (γ-FeO/SiO-Mg(OH)@BC) was synthesized using a hydrothermal method, consisting of γ-FeO, activated sludge biochar (BC), and alkali-modified sepiolite. Its ability to remove heavy metals such as Sb(V), Pb(II), Cd(II), and Zn(II) was investigated through adsorption experiments. Using response surface optimization, the optimal adsorption conditions were determined: adsorption time = 3.
View Article and Find Full Text PDFFood Chem
December 2024
Institute of Food Safety, Chinese Academy of Inspection and Quarantine, Beijing 100176, China; Key Laboratory of Food Quality and Safety for State Market Regulation, Chinese Academy of Inspection and Quarantine, Beijing 100176, China. Electronic address:
An innovative core-shell covalent organic framework (COF), FeO@COF (ETTBA-ND), was synthesized through a facile and energy-efficient method. This adsorbent facilitated magnetic solid phase extraction (MSPE) of six AFs prior to LC-MS/MS analysis, achieving one-step purification and enrichment in food matrices. The successful synthesis of the adsorbent was confirmed using various techniques, with adsorption capacities ranging from 46.
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