Multilayered inclusion nanocycles of anionic spiroborates.

Org Lett

§Kagawa School of Pharmaceutical Sciences, Tokushima Bunri University, 1314-1 Shido, Sanuki, Kagawa 769-2193, Japan.

Published: May 2015

Multilayered spiroborate nanocycles were prepared from tris- or tetrakis(dihydroxynaphthalene) and tetrahydroxyanthraquinone as pillar and crossbar units via the reversible formation of a spiroborate linkage. The four-layered spiroborate nanocycle recognized two cationic aromatic guests simultaneously and exhibited the ability to form a supramolecular one-dimensional array by combining with methyl viologen dimer as the ditopic guest.

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http://dx.doi.org/10.1021/acs.orglett.5b00974DOI Listing

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