Extending previous work [Pusztai et al., Phys. Rev. E 87, 032401 (2013)], we have studied the formation of eutectic dendrites in a model ternary system within the framework of the phase-field theory. We have mapped out the domain in which two-phase dendritic structures grow. With increasing pulling velocity, the following sequence of growth morphologies is observed: flat front lamellae → eutectic colonies → eutectic dendrites → dendrites with target pattern → partitionless dendrites → partitionless flat front. We confirm that the two-phase and one-phase dendrites have similar forms and display a similar scaling of the dendrite tip radius with the interface free energy. It is also found that the possible eutectic patterns include the target pattern, and single- and multiarm spirals, of which the thermal fluctuations choose. The most probable number of spiral arms increases with increasing tip radius and with decreasing kinetic anisotropy. Our numerical simulations confirm that in agreement with the assumptions of a recent analysis of two-phase dendrites [Akamatsu et al., Phys. Rev. Lett. 112, 105502 (2014)], the Jackson-Hunt scaling of the eutectic wavelength with pulling velocity is obeyed in the parameter domain explored, and that the natural eutectic wavelength is proportional to the tip radius of the two-phase dendrites. Finally, we find that it is very difficult/virtually impossible to form spiraling two-phase dendrites without anisotropy, an observation that seems to contradict the expectations of Akamatsu et al. Yet, it cannot be excluded that in isotropic systems, two-phase dendrites are rare events difficult to observe in simulations.
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Soft Matter
January 2025
Department of Chemical Engineering, Indian Institute of Technology Madras, Chennai, Tamil Nadu 600036, India.
In this study, we develop a comprehensive two-phase model to analyze the dynamics of bacterial swarming on porous substrates. The two distinct phases under consideration are the cell and aqueous phases. We use the thin-film approximation, as the characteristic height of the swarm is significantly lower than its characteristic radius.
View Article and Find Full Text PDFJ Colloid Interface Sci
October 2024
Henan Engineering Research Center of Design and Recycle for Advanced Electrochemical Energy Storage Materials, School of Materials Science and Engineering, Henan Normal University, Xinxiang 453007, China; School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan 453007, China; Henan Chaoli New Energy Co., Ltd, Xinxiang 453007, China. Electronic address:
Rechargeable aqueous zinc ion batteries with abundant resources and high safety have gained extensive attention in energy storage technology. However, the cycle stability is largely limited by notorious Zn dendrite growth and water-induced interfacial side reactions. Here, a uniform and robust protection layer consisting of metal antimony (Sb) nanoparticles and micrometer-size sheets Zn(OH)SO·5HO (ZHS) is purposely designed to stabilize Zn anode via an in situ chemical reaction strategy.
View Article and Find Full Text PDFMaterials (Basel)
June 2023
College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063210, China.
Distribution of inclusions plays an essential role in inducing intracrystalline ferrite, and the migration behavior of inclusions during solidification has a significant influence on their distribution. The solidification process of DH36 (ASTMA36) steel and the migration behavior of inclusions at the solidification front were observed in situ using high-temperature laser confocal microscopy. The annexation, rejection, and drift behavior of inclusions in the solid-liquid two-phase region were analyzed, providing a theoretical basis for regulating the distribution of inclusions.
View Article and Find Full Text PDFMaterials (Basel)
May 2023
College of Mechanical and Electric Engineering, Changchun University of Science and Technology, Changchun 130022, China.
To study the corrosion mechanism of high-nitrogen steel welds, this study investigated the effects of laser outputs on the corrosion behavior of high-nitrogen steel hybrid welded joints in hybrid laser-arc welding. The relationship between the ferrite content and laser output was characterized. The ferrite content increased with the increase in the laser power.
View Article and Find Full Text PDFNanomicro Lett
March 2023
State Key Laboratory of Solidification Processing, Centre for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University, Shaanxi Joint Laboratory of Graphene (NPU), Xi'an, 710072, People's Republic of China.
Composite solid electrolytes (CSEs) with poly(ethylene oxide) (PEO) have become fairly prevalent for fabricating high-performance solid-state lithium metal batteries due to their high Li solvating capability, flexible processability and low cost. However, unsatisfactory room-temperature ionic conductivity, weak interfacial compatibility and uncontrollable Li dendrite growth seriously hinder their progress. Enormous efforts have been devoted to combining PEO with ceramics either as fillers or major matrix with the rational design of two-phase architecture, spatial distribution and content, which is anticipated to hold the key to increasing ionic conductivity and resolving interfacial compatibility within CSEs and between CSEs/electrodes.
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