As the desire to explore opaque materials is ordinarily frustrated by multiple scattering of waves, attention has focused on the transmission matrix of the wave field. This matrix gives the fullest account of transmission and conductance and enables the control of the transmitted flux; however, it cannot address the fundamental issue of the spatial profile of eigenchannels of the transmission matrix inside the sample. Here we obtain a universal expression for the average disposition of energy of transmission eigenchannels within random diffusive systems in terms of auxiliary localization lengths determined by the corresponding transmission eigenvalues. The spatial profile of each eigenchannel is shown to be a solution of a generalized diffusion equation. These results reveal the rich structure of transmission eigenchannels and enable the control of the energy distribution inside random media.
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http://dx.doi.org/10.1038/ncomms7893 | DOI Listing |
Nat Commun
December 2024
Department of Physics, Queens College of the City University of New York, Flushing, New York, 11367, USA.
The quantum conductance and its classical wave analogue, the transmittance, are given by the sum of the eigenvalues of the transmission matrix. However, neither measurements nor theoretical analysis of the transmission eigenchannels have been carried out to explain the dips in conductance found in simulations as new channels are introduced. Here, we measure the microwave transmission matrices of random waveguides and find the spectra of all transmission eigenvalues, even at dips in the lowest transmission eigenchannel that are orders of magnitude below the noise in the transmission matrix.
View Article and Find Full Text PDFNat Commun
March 2024
Department of Physics, Queens College of the City University of New York, Flushing, NY, 11367, USA.
The diffusion model is used to calculate both the time-averaged flow of particles in stochastic media and the propagation of waves averaged over ensembles of disordered static configurations. For classical waves exciting static disordered samples, such as a layer of paint or a tissue sample, the flux transmitted through the sample may be dramatically enhanced or suppressed relative to predictions of diffusion theory when the sample is excited by a waveform corresponding to a transmission eigenchannel. Even so, it is widely assumed that the velocity of waves is irretrievably randomized in scattering media.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2024
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu 41566, South Korea.
In order to develop high-performance CNT-based electronic and optoelectronic devices, it is crucial to establish the relationship between the electron transport properties of carbon nanotubes (CNTs) and their structures. In this work, we have investigated the transport properties of chiral (8, ) and (10, ) CNTs sandwiched between two gold electrodes by employing nonequilibrium Green's function (NEGF) combined with density functional theory (DFT). We demonstrate that with the change of chirality the transport property changes, as predicted by the ( - ) rule.
View Article and Find Full Text PDFNano Lett
October 2022
Department of Chemistry, University of Southern California, Los Angeles, California 90089, United States.
Relationships between chemical structure and conductivity in ordered polymers (OPs) are difficult to probe using bulk samples. We propose that conductance measurements of appropriate molecular-scale models can reveal trends in electronic coupling(s) between repeat units that may help inform OP design. Here, we apply the scanning tunneling microscope-based break-junction (STM-BJ) method to study transport through single-molecules comprising OP-relevant imine, imidazole, diazaborole, and boronate ester dynamic covalent chemical bridges.
View Article and Find Full Text PDFNature
July 2022
Université de Rennes, CNRS, IETR (Institut d'Électronique et des Technologies du numéRique), UMR-6164, Rennes, France.
The scattering of waves when they propagate through disordered media is an important limitation for a range of applications, including telecommunications, biomedical imaging, seismology and material engineering. Wavefront shaping techniques can reduce the effect of wave scattering, even in opaque media, by engineering specific modes-termed open transmission eigenchannels-through which waves are funnelled across a disordered medium without any back reflection. However, with such channels being very scarce, one cannot use them to render an opaque sample perfectly transmitting for any incident light field.
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