Crystal structure of bis-(2-{[(3-bromo-prop-yl)imino]-meth-yl}phenolato-κ(2) N,O)copper(II).

Acta Crystallogr E Crystallogr Commun

Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale, CHEMS, Université Constantine 1, 25000 , Algeria.

Published: February 2015

In the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the mol-ecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu-O and Cu-N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual mol-ecules are packed in alternating zigzag layers parallel to (001). Weak C-H⋯π inter-actions exist between the mol-ecules.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384597PMC
http://dx.doi.org/10.1107/S2056989015001309DOI Listing

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