Crystal structure of 2-benzyl-amino-4-p-tolyl-6,7-di-hydro-5H-cyclo-penta-[b]pyridine-3-carbo-nitrile.

Acta Crystallogr E Crystallogr Commun

Department of Food Science and Technology, University of Ruhuna, Mapalana, Kamburupitiya 81100, Sri Lanka.

Published: February 2015

The title compound, C23H21N3, comprises a 2-amino-3-cyano-pyridine ring fused with a cyclo-pentane ring. The later adopts an envelope conformation with the central methyl-ene C atom as the flap. The benzyl and and p-tolyl rings are inclined to one another by 56.18 (15)°, and to the pyridine ring by 81.87 (14) and 47.60 (11)°, respectively. In the crystal, mol-ecules are linked by pairs of N-H⋯Nnitrile hydrogen bonds, forming inversion dimers with an R 2 (2)(12) ring motif. The dimers are linked by C-H⋯π and π-π inter-actions [centroid-centroid distance = 3.7211 (12) Å], forming a three-dimensional framework.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384633PMC
http://dx.doi.org/10.1107/S2056989015000572DOI Listing

Publication Analysis

Top Keywords

crystal structure
4
structure 2-benzyl-amino-4-p-tolyl-67-di-hydro-5h-cyclo-penta-[b]pyridine-3-carbo-nitrile
4
2-benzyl-amino-4-p-tolyl-67-di-hydro-5h-cyclo-penta-[b]pyridine-3-carbo-nitrile title
4
title compound
4
compound c23h21n3
4
c23h21n3 comprises
4
comprises 2-amino-3-cyano-pyridine
4
ring
4
2-amino-3-cyano-pyridine ring
4
ring fused
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!