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Residual entropy and waterlike anomalies in the repulsive one dimensional lattice gas. | LitMetric

Residual entropy and waterlike anomalies in the repulsive one dimensional lattice gas.

J Chem Phys

Programa de Pós-Graduação em Ciência de Materiais, Faculdade UnB Planaltina, Universidade de Brasília, Planaltina-DF, Brazil.

Published: April 2015

AI Article Synopsis

  • The study explores the thermodynamics and kinetics of a one-dimensional lattice gas with repulsive interactions using transfer matrix techniques and Monte Carlo simulations.
  • This model demonstrates water-like anomalies, including unusual behavior in density, thermal expansion coefficient, and self-diffusion.
  • A unified explanation for these thermodynamic anomalies is provided, linking them to the ground state residual entropy resulting from mixing entropy during a phase transition.

Article Abstract

The thermodynamics and kinetics of the one dimensional lattice gas with repulsive interaction are investigated using transfer matrix technique and Monte Carlo simulations. This simple model is shown to exhibit waterlike anomalies in density, thermal expansion coefficient, and self-diffusion. An unified description for the thermodynamic anomalies in this model is achieved based on the ground state residual entropy which appears in the model due to mixing entropy in a ground state phase transition.

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Source
http://dx.doi.org/10.1063/1.4916905DOI Listing

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