A tetranuclear copper cluster-based MOF with sulfonate-carboxylate ligands has been synthesized. It possesses one-dimensional irregular channels lined with sulfonate, carboxylate, and DMF molecules, which show a high proton conductivity of 7.4 × 10(-4) S cm(-1) at 95 °C and 95% relative humidity.
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http://dx.doi.org/10.1039/c5cc01732g | DOI Listing |
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