In this communication, we show that the combination of 1 M lithium bis(trifluoromethylsulfonyl)amide and 1-butyl-1-methylpyrrolidinium bis(fluorosulfonyl)amide (LiTFSI/[Py1,4]FSI) can be regarded as a possible stable electrolyte for IL based lithium ion batteries. We compare the charge-discharge results with the electrolyte 1 M LiTFSI in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide ([Py1,4]TFSI) on an electrodeposited Ge electrode and show using a charge-discharge analysis and Raman spectroscopy that 1 M LiTFSI/[Py1,4]FSI is advantageous in maintaining the charge capacity as well as electrolyte stability at high current densities.
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http://dx.doi.org/10.1039/c5cp01337b | DOI Listing |
ACS Appl Mater Interfaces
April 2024
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Yaguan Road 135, Tianjin 300350, P. R. China.
High-voltage resistant quasi-solid-state polymer electrolytes (QSPEs) are promising for enhancing the energy density of lithium-metal batteries in practice. However, side reactions occurring at the interfaces between the anodes or cathodes and QSPEs considerably reduce the lifespan of high-voltage LMBs. In this study, a copolymer of vinyl ethylene carbonate (VEC) and poly(ethylene glycol) diacrylate (PEGDA) was used as the framework, with a cellulose membrane (CE) as the supporting layer.
View Article and Find Full Text PDFPolymers (Basel)
August 2022
School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China.
Solid-state polymer electrolytes have become promising candidates for high-energy-density lithium metal batteries (LMBs). However, they suffer from low ionic conductivities at room temperature. In this work, two types of composite polymer electrolytes based on a double-network polymer, an ionic liquid (IL) of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (PyrTFSI) or 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl) imide (EmimTFSI), and bis(trifluoromethane)sulfonamide lithium salt (LiTFSI) were prepared by a facile one-pot method.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2020
Leibniz Institute for Solid State and Materials Research (IFW) Dresden e.V., Helmholtzstr. 20, 01069 Dresden, Germany.
Electrode materials with a high performance and stable cycling have been commercialized, but the utilization of state-of-the-art Li-ion batteries in high-current rate applications is restricted because of limitations in other battery components, in particular, the lack of an efficient binder. Herein, a novel multicomponent polymer gel binder (PGB) is presented, comprising the biopolymer chitosan as the host, embedded with the 1-butyl-1-methylpyrrolidinium dicyanamide (PYRDCA) ionic liquid and the lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt. The multicomponent approach leads to carbon black arrangement along well-distributed chitosan chains in the electrodes, forming a highly electronic conductive network.
View Article and Find Full Text PDFACS Appl Mater Interfaces
April 2020
Samsung Advanced Institute of Technology (SAIT), Samsung Future Technology Campus, Samsung Electronics Company, Ltd., 130 Samsung-ro, Maetan-dong, Yeongtong-gu, Suwon-si, Gyeonggi-do 443-803, Republic of Korea.
Li-O batteries have attracted considerable attention for several decades due to their high theoretical energy density (>3400 Wh/kg). However, it has not been clearly demonstrated that their actual volumetric and gravimetric energy densities are higher than those of Li-ion batteries. In previous studies, a considerable quantity of electrolyte was usually employed in preparing Li-O cells.
View Article and Find Full Text PDFChemSusChem
May 2020
Helmholtz-Institute Ulm (HIU) Electrochemical Energy Storage, Helmholtzstraße 11, 89081, Ulm, Germany.
The process of solid-electrolyte interphase (SEI) formation is systematically investigated along with its chemical composition on carbon electrodes in an ionic liquid-based, Li-containing electrolyte in a combined surface science and electrochemical model study using highly oriented pyrolytic graphite (HOPG) and binder-free graphite powder electrodes (Mage) as model systems. The chemical decomposition process is explored by deposition of Li on a pre-deposited multilayer film of 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([BMP][TFSI]) under ultrahigh vacuum conditions. Electrochemical SEI formation is induced by and monitored during potential cycling in [BMP][TFSI]+0.
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