The synthesis, structural, electronic and magnetic characterization of five dinuclear Co(II) azacryptand compounds (1-5) bridged through different ions are reported. The magnetic exchange interactions, 2J values, obtained from theoretical computations show that the variation of the intermetallic angles and distances lead to antiferromagnetic behaviours. Magneto-structural correlations show a trend, where the angles Co(II)-bridge-Co(II) closer to 180° favour an increase in the superexchange pathway leading to higher AF interaction values.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c5dt00497g | DOI Listing |
Publication Analysis
Top Keywords
dinuclear coii
8
inducing magnetic
4
magnetic communication
4
communication caged
4
caged dinuclear
4
coii systems
4
systems synthesis
4
synthesis structural
4
structural electronic
4
electronic magnetic
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!