AI Article Synopsis
- Potassium rubidium cobalt(II)/titanium(IV) tris-(orthophosphate) was synthesized using a high-temperature crystallization technique.
- The compound features a langbeinite-type structure, combining mixed Co/Ti(IV) octahedra and PO4 tetrahedra in a three-dimensional framework.
- K(+) and Rb(+) cations are randomly distributed in large cavities, with each surrounded by 12 oxygen atoms.
Article Abstract
Potassium rubidium cobalt(II)/titanium(IV) tris-(orthophosphate), Rb0.743K0.845Co0.293Ti1.707(PO4)3, has been obtained using a high-temperature crystallization method. The obtained compound has a langbeinite-type structure. The three-dimensional framework is built up from mixed-occupied (Co/Ti(IV))O6 octa-hedra (point group symmetry .3.) and PO4 tetra-hedra. The K(+) and Rb(+) cations are statistically distributed over two distinct sites (both with site symmetry .3.) in the large cavities of the framework. They are surrounded by 12 O atoms.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350725 | PMC |
| http://dx.doi.org/10.1107/S2056989015001826 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
A twofold interpenetrated three-dimensional barium(II) metal-organic framework constructed from 2,2'-[terephthaloylbis(azanediyl)]diacetate: synthesis, structure, dihydrogen bonding and spectroscopic properties.
Acta Crystallogr C Struct Chem
January 2025
College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, People's Republic of China.
A new twofold interpenetrated 3D metal-organic framework (MOF), namely, poly[[μ-aqua-diaqua{μ-2,2'-[terephthaloylbis(azanediyl)]diacetato}barium(II)] dihydrate], {[Ba(CHNO)(HO)]·2HO}, (I), has been assembled through a combination of the reaction of 2,2'-[terephthaloylbis(azanediyl)]diacetic acid (TPBA, HL) with barium hydroxide and crystallization at low temperature. In the crystal structure of (I), the nine-coordinated Ba ions are bridged by two μ-aqua ligands and two carboxylate μ-O atoms to form a 1D loop-like Ba-O chain, which, together with the other two coordinated water molecules and μ-carboxylate groups, produces a rod-like secondary building unit (SBU). The resultant 1D polynuclear SBUs are further extended into a 3D MOF via the terephthalamide moiety of the ligand as a spacer.
View Article and Find Full Text PDFEnd-to-End Crystal Structure Prediction from Powder X-Ray Diffraction.
Adv Sci (Weinh)
January 2025
DP Technology, Beijing, 100080, China.
Powder X-ray diffraction (PXRD) is a prevalent technique in materials characterization. While the analysis of PXRD often requires extensive human manual intervention, and most automated method only achieved at coarse-grained level. The more difficult and important task of fine-grained crystal structure prediction from PXRD remains unaddressed.
View Article and Find Full Text PDFCsAgBiBr and related Halide double perovskite porous single crystals.
Sci Rep
January 2025
Multifunctional Materials Laboratory, Department of Physics, Indian Institute of Technology Madras, Chennai, 600036, India.
The utilization of single crystals is exponentially growing in optoelectronic devices due to their exceptional benefits, including high phase purity and the absence of grain boundaries. However, achieving single crystals with a porous structure poses significant challenges. In this study, we present a method for fabricating porous single crystals (porous-SC) of CsAgBiBr and related halide double perovskites using an infrared-assisted spin coating technique.
View Article and Find Full Text PDFAdaptable electro-optic detection of THz radiation using a laser-written bull's-eye antenna.
Sci Rep
January 2025
Department of Physics, University of Ottawa, Ottawa, ON, K1N 6N5, Canada.
We report a nonlinear terahertz (THz) detection device based on a metallic bull's-eye plasmonic antenna. The antenna, fabricated with femtosecond laser direct writing and deposited on a nonlinear gallium phosphide (GaP) crystal, focuses incoming THz waveforms within the sub-wavelength bull's eye region to locally enhance the THz field. Additionally, the plasmonic structure minimizes diffraction effects allowing a relatively long interaction length between the transmitted THz field and the co-propagating near-infrared gating pulse used in an electro-optic sampling configuration.
View Article and Find Full Text PDFMicrostructure and properties of joint of Al/Cu welded by resistance element welding with an auxiliary gasket of Ni.
Sci Rep
January 2025
College of Material Science and Engineering, Henan Institute of Technology, Xinxiang, 453003, China.
A rivet of aluminum and auxiliary gasket of nickel were adopted to weld A1060 aluminum plate and T2 copper plate using resistance element welding. The interfacial microstructure was analyzed and the tensile shear load of the joint was tested. A layer of AlCu and the eutectic structure of AlCu and (Al) were formed in the interfacial zone of Al/Cu.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!