The combination of the N-based pincer ligand PyBOX with Pt leads to new catalysts for the enantioselective cycloisomerization of dienyl- and trienyl-ols. The mechanistic combination of electrophilic cyclization followed by rapid protodemetalation is surprising and leads to a powerful construct for developing new reactions.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4372115 | PMC |
| http://dx.doi.org/10.1021/cs401190c | DOI Listing |
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