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Rebuttal From Drs Atkins and Das.
Chest
August 2024
Department of Political Science, University of Toronto, Toronto, ON, Canada; Division of Neurosurgery, Department of Surgery, University of Toronto, Toronto, ON, Canada.
Rebuttal From Drs Adrish and Hanania.
Chest
July 2024
Section of Pulmonary, Critical Care and Sleep Medicine, Baylor College of Medicine, Houston, TX. Electronic address:
Rebuttal to the article Pathological crystal structures.
Acta Crystallogr C Struct Chem
July 2024
Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA.
A section in the Acta Crystallographica Section C article by Raymond & Girolami [Acta Cryst. (2023), C79, 445-455] stated that the product of the reaction of [(Cp*Rh)(μ-OH)] (Cp* is 1,2,3,4,5-pentamethylcyclopentadiene) with 1-methylthymine (1-MT) at pH 10 and 60 °C, to synthesize the anionic component [Rh(η-N-1-MT)], was not an Rh complex, but rather an Ag complex, due to the use of silver triflate (AgOTf) to remove Cl from [Cp*RhCl] to synthesize [Cp*Rh(HO)](OTf), a water-soluble crystalline complex. We will clearly show that this premise, as stated, is invalid, while the authors have simply avoided several important facts, including that Cp*OH, a reductive elimination product, at pH 10 and 60 °C, was unequivocally identified, thus leading to the Rh anionic component [Rh(η-N-1-MT)].
View Article and Find Full Text PDFRebuttal From Drs Fein, Taylor, and Stempek.
Chest
June 2024
Division of Pulmonary & Critical Care Medicine, Lahey Hospital & Medical Center, Burlington, MA.
Rebuttal From Drs Resnick-Ault, Gandotra, and Gaillard.
Chest
June 2024
Department of Anesthesiology, Section on Critical Care, Department of Emergency Medicine, Wake Forest School of Medicine, Winston-Salem, NC.
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