A rhodium(I)-catalysed formal intramolecular C-C/C-H bond metathesis.

Chem Commun (Camb)

Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan.

Published: April 2015

Phenylcyclobutanes underwent skeletal reorganisation in the presence of Wilkinson's catalyst to afford indanes through a cascade process involving chelation-assisted C-C bond cleavage and intramolecular C-H bond cleavage.

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Source
http://dx.doi.org/10.1039/c5cc01415hDOI Listing

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