Palladium-catalyzed oxidative synthesis of highly functionalized ortholactones.

Chemistry

School of Chemistry and Chemical Engineering, Queen's University Belfast, Belfast, BT9 5AG (UK).

Published: May 2015

A palladium-catalyzed oxidative reaction is reported which converts dihydropyrans to their corresponding ortholactone. The products are formed in good to excellent yields with a very high level of chemoselectivity and functional group tolerance. Mechanistic studies confirm that the reaction proceeds by a Wacker-type mechanism.

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http://dx.doi.org/10.1002/chem.201500862DOI Listing

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