Magnetocaloric effect and thermal conductivity of Gd(OH)3 and Gd2O(OH)4(H2O)2.

Chem Commun (Camb)

Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.

Published: April 2015

Magnetocaloric effect (MCE) and thermal conductivity of two gadolinium hydroxides, Gd(OH)3 (1) and Gd2O(OH)4(H2O)2 (2), are investigated. Magnetic studies indicate that both 1 and 2 exhibit antiferromagnetic interaction, and the MCE values for 1 and 2 at 2 K and ΔH = 7 T are 62.00 J kg(-1) K(-1) and 59.09 J kg(-1) K(-1), respectively. Investigation of their thermal conductivity reveals that the thermal conductivity for 1 is significantly better than that for 2.

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Source
http://dx.doi.org/10.1039/c5cc01254fDOI Listing

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