It has been shown that the relative stabilities of various superfluid states of ^{3}He can be influenced by anisotropy in a silica aerogel framework. We prepared a suite of aerogel samples compressed up to 30% for which we performed pulsed NMR on ^{3}He imbibed within the aerogel. We identified A and B phases and determined their magnetic field-temperature phase diagrams as a function of strain. From these results, we infer that the B phase is distorted by negative strain forming an anisotropic superfluid state more stable than the A phase.
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http://dx.doi.org/10.1103/PhysRevLett.114.105302 | DOI Listing |
Chem Sci
December 2024
Key Laboratory of Precision and Intelligent Chemistry, University of Science and Technology of China Hefei Anhui 230026 China
The packing of organic molecular crystals is often dominated by weak non-covalent interactions, making their rearrangement under external stimuli challenging to understand. We investigate a pressure-induced single-crystal-to-single-crystal (SCSC) transformation between two polymorphs of 2,4,5-triiodo-1-imidazole using machine learning potentials. This process involves the rearrangement of halogen and hydrogen bonds combined with proton transfer within a complex solid-state system.
View Article and Find Full Text PDFAcc Chem Res
January 2025
Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada.
ConspectusStructural DNA nanotechnology offers a unique self-assembly toolbox to construct soft materials of arbitrary complexity, through bottom-up approaches including DNA origami, brick, wireframe, and tile-based assemblies. This toolbox can be expanded by incorporating interactions orthogonal to DNA base-pairing such as metal coordination, small molecule hydrogen bonding, π-stacking, fluorophilic interactions, or the hydrophobic effect. These interactions allow for hierarchical and long-range organization in DNA supramolecular assemblies through a DNA-minimal approach: the use of fewer unique DNA sequences to make complex structures.
View Article and Find Full Text PDFMolecules
December 2024
Faculty of Physics, Alexandru Ioan Cuza University, 11 Carol I Blvd, RO-700506 Iasi, Romania.
A rapid and simple spectral method for determining the linear birefringence of thin anisotropic films, using the channeled spectra, is proposed in this article. Two channeled spectra must be recorded for a transparent system containing a thick anisotropic layer and a thin stretched polymer film, when the two anisotropic uniaxial layers have parallel and perpendicular optical axes, respectively. The sum and difference of the two channeled spectra indicate (by the positions of the maxima and minima in the resulting channeled spectra) the phase difference introduced by the thin polymer film.
View Article and Find Full Text PDFEntropy (Basel)
December 2024
Department of Physics, Federal Technological Education Center of Minas Gerais, Belo Horizonte 30510-000, MG, Brazil.
In this paper, we analyzed the influence of the spin Nernst effect on quantum correlation in a layered ferrimagnetic model. In the study of three-dimensional ferrimagnets, the focus is on materials with a specific arrangement of spins, where the neighboring spins are parallel and the others are antiparallel. The anisotropic nature of these materials means that the interactions between spins depend on their relative orientations in different directions.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Helmholtz Institute Erlangen-Nürnberg for Renewable Energy, Forschungszentrum Jülich, Fürther Strasse 248, 90429 Nürnberg, Germany.
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