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Stereochemical studies of the opening of chloro vinyl epoxides: cyclic chloronium ions as intermediates. | LitMetric

Stereochemical studies of the opening of chloro vinyl epoxides: cyclic chloronium ions as intermediates.

Org Lett

Department of Chemistry and Applied Biosciences, Laboratorium für Organische Chemie, Eidgenössische Technische Hochschule Zürich, Vladimir-Prelog-Weg 3, CH-8093 Zürich, Switzerland.

Published: April 2015

AI Article Synopsis

Article Abstract

A systematic study of the opening of a collection of chlorinated vinyl epoxides is reported, which includes experiments that implicate both five- and four-membered chloronium ions as plausible intermediates in this type of epoxide opening reaction.

Download full-text PDF

Source
http://dx.doi.org/10.1021/acs.orglett.5b00558DOI Listing

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